This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1907 Excerpt: ...constants of our apparatus varied in an irregular and unexplained manner from time to time in much the same way as described by Bousfield8 in his researches. We therefore made it a point to determine its constants with water immediately before and after every series of measurements. If the constants were found to have ...
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This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1907 Excerpt: ...constants of our apparatus varied in an irregular and unexplained manner from time to time in much the same way as described by Bousfield8 in his researches. We therefore made it a point to determine its constants with water immediately before and after every series of measurements. If the constants were found to have changed by over 0.75 per cent., the measurement was discarded. The agreement was usually much better than this, in which case the mean value of the constants before and after the run was taken in the computation. 2 For discussion of corrections applied see unabridged article. 3 W. R. Bousfield. Zeit, fur Thys. Chem., J.?, 257, 1905. Summary of Results. The final results of our investigation may be summarized as follows: 1. The curves representing the change of density with the temperature of sodium, potassium, lithium, and silver nitrate and silver chlorate, together with mixtures of sodium and potassium nitrate and of lithium nitrate and silver chlorate are shown in Plots I, II, and III. 2.001 1 1 1 1 1 1 1 1 In all cases, the density is a linear function of the temperature over the range of temperature investigated, to within a tenth of a per cent. From these curves, tables giving the specific and molecular volume for every ten degrees have been computed. 2. The specific volume of mixtures of sodium and potassium nitrate, containing 8 and 2, 5 and 5, and 2 and 8 mols of these salts respectively, is greater than that computed from the specific volumes of the components, i. e., the solution of one salt in another is accompanied by an expansion. The magnitude of this expansion is small, being a maximum, 0.5 per cent., for the equimolecular mixture. In the case of an equimolecular mixture of lithium nitrate and silver chlorate, on the other hand...
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