This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1920 Excerpt: ...in obtaining a crystalline compound which had the composition 2 AlCl3.2 C6H3CH(CH3)23.HC1 C.r. lJfi, 940 (1905); J. pr. Chem. 72, 57 (1905), but this does not conform to the above type and is really a ternary compound. B. N. Menschutkin J. Russ. Phys. Chem. Soc. 41, 1089 (1909); Chem. Zentralb. 1910, 1, 167 showed that ...
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This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1920 Excerpt: ...in obtaining a crystalline compound which had the composition 2 AlCl3.2 C6H3CH(CH3)23.HC1 C.r. lJfi, 940 (1905); J. pr. Chem. 72, 57 (1905), but this does not conform to the above type and is really a ternary compound. B. N. Menschutkin J. Russ. Phys. Chem. Soc. 41, 1089 (1909); Chem. Zentralb. 1910, 1, 167 showed that the freezing point curves of mixtures of aluminium halides and benzene or toluene gave no indication of the formation of any such addition compounds as claimed by Gustavson. Many chemists are inclined to accept the results of Menschutkin as conclusive evidence that aluminium halides and benzene or toluene do not form any addition compounds. On the other hand, all that the freezing point curve shows under these conditions is that, even if formed, not enough of the addition compound was present to saturate the solution. Furthermore, Menschutkin found that in the case of other metal halides such as antimony chloride, addition compounds such as SbCl3.C6H6 can be obtained C. A. (1911) 1434). It must also be borne in mind in comparing these results with the results of Gustavson, that the latter in his experiments had hydrogen chloride present as well.. J. Boeseken and co-workers Rec. trav. chim. 32, 184 (1913); 33,317; 34,78; 37,109; Verslag Akad. Wenschappen 21, 979 studied the Friedel-Crafts reaction in connection with sulfonyl chlorides such as p-brombenzenesulphonechloride, etc. These combined with the aluminium chloride. The resulting compounds then reacted with the aromatic hydrocarbon. The sulfone formed in the reaction combined with the aluminium chloride, and if formed in considerable amount decreased the velocity of the reaction by decreasing the concentration of the double salt of the sulfone chloride and aluminium chloride. There is con...
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Add this copy of Chemical Reactions: Their Theory and Mechanism to cart. $50.90, new condition, Sold by Media Smart rated 4.0 out of 5 stars, ships from Hawthorne, CA, UNITED STATES, published 2019 by Wentworth Press.
Add this copy of Chemical Reactions: Their Theory and Mechanism to cart. $58.41, good condition, Sold by Bonita rated 4.0 out of 5 stars, ships from Newport Coast, CA, UNITED STATES, published 2019 by Wentworth Press.
