This historic book may have numerous typos and missing text. Purchasers can usually download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1892 edition. Excerpt: ...odour, resembling that of phenylphosphine, and boils with decomposition above 360. It unites with ethyl iodideto form tridhylriaphthylphosphmiumiodtec, CwYL.'2(CJ&. which crystallizes from water in well-formed plates, melting at 2090.1 1 Ber. 9, 1051; U, 1499. ARSENIC DERIVATIVES OF NAPHTHYL. 2672 ...
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This historic book may have numerous typos and missing text. Purchasers can usually download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1892 edition. Excerpt: ...odour, resembling that of phenylphosphine, and boils with decomposition above 360. It unites with ethyl iodideto form tridhylriaphthylphosphmiumiodtec, CwYL.'2(CJ&. which crystallizes from water in well-formed plates, melting at 2090.1 1 Ber. 9, 1051; U, 1499. ARSENIC DERIVATIVES OF NAPHTHYL. 2672 Naphthylarsenious chloride, C10H7AsCl2, is obtained by the action of arsenic trichloride on mercurynaphthyl. It is a white crystalline powder, melts at 63, and is readily soluble in alcohol, but insoluble in water, and is not decomposed by the latter even on heating. Naphthylarsenious oxide, C10H7AsO, is formed by the decomposition of the chloride by alkalis as a white powder, which melts at 245, and is insoluble in water, slightly soluble in alcohol1 Naphthylarsinic acid, C10H7AsO(OH)2, is obtained by the action of chlorine and water on the chloride, and crystallizes in well-formed needles, melting at 197 (Kelbe). Arsenonaphlhalenc, (C10H7)2As2, is prepared by heating the oxide with alcohol and solid phosphorous acid: C10H7As 2C10H7AsO + 2P03H3 = 11+2 P04H3. It is a powder which consists of slender yellow needles, melts at 221, is sparingly soluble in alcohol, insoluble in water, and combines with chlorine to form naphthylarsenious chloride. MERCURY DERIVATIVES OF NAPHTHALENE. 2673 Mercurynaphthyl, Hg(C10H7)2, is obtained by heating a-bromonaphthalene with pasty sodium amalgam, coal-tar naphtha boiling at 120--140 and a little ethyl acetate. It crystallizes in small, lustrous rhombic prisms, which melt at 243 and are odourless. It is only slightly soluble in boiling alcohol, more freely in boiling benzene, and readily in hot chloroform and carbon disulphide. On heating with concentrated hydrochloric acid, naphthalene and mercuric chloride...
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Add this copy of A Treatise on Chemistry Volume 2: 1 to cart. $59.69, good condition, Sold by Bonita rated 4.0 out of 5 stars, ships from Newport Coast, CA, UNITED STATES, published 2010 by Nabu Press.